The fact that the effective permeability k¯
has dimensions of area raises the question whether
k¯ has an interpretation as a length
scale.
The traditional answer to this question is provided
by hydraulic radius theory which uses the approximate
result (5.61) for the capillary tube model
to postulate more generally the relation
where RH=ϕ𝕊/S𝕊 is the hydraulic
radius.
This generalization has been modified by incorporating the
formation factor to write [327, 112]
where the length scale Λ=RH is still given
by the hydraulic radius, and the geometrical tortuosity
𝒯2 was replaced by the electrical tortuosity defined as
𝒯el2=Fϕ¯.
Because the length scale is still given by the hydraulic
radius this theory is still faced with the objection that
the hydraulic radius RH contains contributions from
the dead ends which do not contribute to the transport.
An alternative was proposed in [318, 43].
It postulates Λ=lc where lc is a length scale
related to the breakthrough pressure in mercury injection
experiments.
The length scale lc is well defined for network models
with a broad distribution of cylindrical pores.
A dynamical interpretation of Λ was proposed in
[319, 320, 328] as
2Λ=∫Er2χ∂ℙrd2r∫Er2χℙrd3r |
| (5.100) |
where Er is the unknown exact solution of the
microscopic dielectric problem.
This “electrical length” is expected to measure,
somehow, the “dynamically connected pore size
[319, 328, 4].
The interpretation of Λ within local porosity
theory is obtained by eliminating p-pc between
the result (5.48) for the conductivity, and
equation (5.95) for the permeability.
This yields in general
Λ2≈∫0∞∫01λϕ,S;𝕂μϕ,S;𝕂σlocϕ,SdϕdS∫0∞∫01λϕ,S;𝕂μϕ,S;𝕂klocϕ,SdϕdS |
| (5.101) |
where σlocϕ,S and klocϕ,S are
the local electrical conductivity and the local permeability.
Thus Λ involves macroscopic geometrical information
through μ and λ and microscopic dynamical and
geometrical information through the local transport coefficients.
If one assumes the hydraulic radius expressions
σlocϕ,S∝ϕ and
klocϕ,S∝ϕ3/S2 locally
and the expression
μ(ϕ,S;𝕂)≈δ(ϕ-ϕ)¯δ(S-S¯)
valid for large measurment cells, then it follows that
Λ∝ϕ¯/S¯ becomes the
local hydraulic radius [170].
This expression is no longer proportional to the total
internal surface but only to the average local internal
surface, and thus the argument against hydraulic radius
theories no longer apply.