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# 4 Dynamic Disorder: Renewal Approach

[188.1.1] So far we have discussed equation (2.1). [188.1.2] We now turn to equation (2.9), i. e.  we consider dynamic disorder. [188.1.3] The difficulty lies not so much in solving eq. (2.9) but in specifying the stochastic coefficients At. [188.1.4] They are determined by the random motion of all blockers. [188.1.5] Our general strategy will be to assume a simpler form for the random process At, and then to find a solution for eq. (2.9) which makes use of the solution for the frozen case, i. e.  eq. (2.1).

[188.2.1] The basic idea is to approximate the actual correlated dynamics of the environment by a simple exponential renewal process. [188.2.2] Consider a single bond. [188.2.3] It is either occupied or vacant, and switches randomly between these two states. [188.2.4] This can be modelled by a two state Markov chain as suggested by Harrison and Zwanzig[30]. [188.2.5] Let 1/τr, be the switching frequency between the two states, i. e.  τr is an effective renewal time. [188.2.6] Then the probability to find the bond occupied by a blocker at time t is easily seen to relax as p+p0exp-t/τr, where p0, is either 1-p or -p depending upon whether at time 0 the bond was occupied or not. [188.2.7] Thus, in this model, the bonds flip randomly and independently between the two states. [188.2.8] Using a 1-bond effective medium approximation, as the one described above, Harrison and Zwanzig[30] have shown that for this model the generalized diffusion coefficient is given by D0u+1/τr where D0u is the diffusion coefficient for the corresponding frozen problem (e. g. eq. (3.13)). [188.2.9] The same result, to which we will refer as the substitution rule, had been obtained by Druger, Ratner and Nitzan[31] for a model in which full configurations are renewed instead of single bonds. [188.2.10] This is not surprising because in the 1-bond-approximation the behaviour for the full lattice is calculated by considering only the possible configurations of a single bond. [188.2.11] Let us therefore approximate the dynamics of the environment by an exponential renewal process for full lattice configurations with renewal density

 ψr⁢t=1τr⁢e-t/τr. (4.1)

[page 189, §0]    [189.0.1] The mean renewal time τr is now an effective renewal time which should be proportional to τ, the ratio of jump rates between B- and A-particles, i. e.

 τr=c⁢τ. (4.2)

[189.0.2] The proportionality constant c contains the effects from correlations in the blocker dynamics that are not taken into account by the renewal approach. [189.0.3] It is, however, not an adjustable parameter. [189.0.4] It will be determined below by comparison with well known exact results for the limit p1(τ=1,b=1). [189.0.5] The substitution rule can also be obtained from a simple probabilistic argument[22]. [189.0.6] Consider the inverse Laplace transform D0t of D0u which was calculated in eq. (3.13). [189.0.7] As is well known, D0t is the kernel of a generalized master equation[32]. [189.0.8] Therefore it can be interpreted as a generalized time dependent transition rate, i. e.  transition probability per unit time. [189.0.9] It describes the frozen problem in a mean field picture and is the proper kernel to use between renewal events. [189.0.10] Because the renewal process and the random walk of the Aâparticle are independent, the transition rate for the dynamic problem at time t is the product of the corresponding rate for the frozen case and the probability that there was no renewal up to time t, i. e.

 D⁢t=D0⁢t⁢1-∫0tψr⁢t′⁢d⁢t′=D0⁢t⁢e-t/τr. (4.3)

[189.0.11] From this one recovers the substitution rule by Laplace transformation. [189.0.12] Using eq. (4.2) we get

 D⁢u=D0⁢u+1c⁢τ (4.4)

as our final result.

[189.1.1] To proceed we have to specify a particular lattice of interest, and solve eq. (3.10). [189.1.2] Before doing so we comment briefly on the relation to our previous continuous time random walk approach to the same problem[22]. [page 190, §0]    [190.0.1] Here, as in our previous work we have attempted to find a framework in which correlation effects resulting purely from the dynamics of the environment can be incorporated. [190.0.2] In the present paper we have attacked the problem by considering random walks with memory which has the additional advantage that other types of correlations can be considered. [190.0.3] In our previous CTRW-approach we have attempted to incorporate correlation effects into the waiting time distribution by way of crude probabilistic and physical arguments about the nature of the deblocking mechanism. [190.0.4] This was based on the fact that the effective medium waiting time distribution below pc is not normalized. [190.0.5] Consequently the distinction between the case above pc and below persisted, and it was necessary to utilize the substitution rule of eq. (4.3) to treat the case above pc. [190.0.6] In addition our previous approach was limited to the case τ1. [190.0.7] Its main advantage was to exhibit the theoretical possibility of a sequential deblocking mechanism resulting in a nonmonotonous waiting time density and interesting consequences for the conductivity. [190.0.8] On the other hand our present approach applies for all τ and p. [190.0.9] It allows for other sources of correlations, and gives relatively good quantitative results. [190.0.10] This will be demonstrated in the next section.