Difference between revisions of "Ferrofluids"

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(Why are Ferrofluids interesting?)
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__NOTOC__
 
__NOTOC__
[[Image:Pferro1.gif|300px|right|thumb|Ferrofluid monolayer at low area fraction.]]
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[[Image:Pferro1.gif|300px|right|thumb|Fig1. Ferrofluid monolayer at low area fraction.]]
[[Image:Pferro2.gif|300px|right|thumb|Ferrofluid monolayer at high area fraction.]]
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[[Image:Pferro2.gif|300px|right|thumb|Fig2. Ferrofluid monolayer at high area fraction.]]
  
 
'''Ferrofluids'''  under construction
 
'''Ferrofluids'''  under construction
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* The singular properties of ferrofluids in external magnetic fields  have found application in many areas, ranging from engineering,  to biomedical applications in  cancer treatment (Rosensweig1985, Odenbach2002, Alexiou2003,Hilger2004, Scherer2005). Just a few examples:
 
* The singular properties of ferrofluids in external magnetic fields  have found application in many areas, ranging from engineering,  to biomedical applications in  cancer treatment (Rosensweig1985, Odenbach2002, Alexiou2003,Hilger2004, Scherer2005). Just a few examples:
 
** [http://www.machinedesign.com/ASP/strArticleID/57965/strSite/MDSite/viewSelectedArticle.asp Magnetic Seals] for instance in  [http://www.lesker.com/newweb/Sample_Manipulation/samplemanip_technicalnotes_1.cfm vaccum pumps].
 
** [http://www.machinedesign.com/ASP/strArticleID/57965/strSite/MDSite/viewSelectedArticle.asp Magnetic Seals] for instance in  [http://www.lesker.com/newweb/Sample_Manipulation/samplemanip_technicalnotes_1.cfm vaccum pumps].
** [http://www.carbibles.com/images/magneride.jpg Car dampers],  
+
** [http://www.carbibles.com/images/magneride.jpg Car dampers], [http://www.iwf.tu-berlin.de/fachgebiete/wzm/forschung/forschung3/Magnetofluidisches%20Positioniersystem/view?searchterm=Hipper  nanoactuators], [http://www.ferrotec.com/products/ferrofluid/audio/audioBenefits.php loudspeakers], [http://wood.phy.ulaval.ca/ferrofluids/homemade.php adaptive optics (liquid mirrors)],  
[http://www.iwf.tu-berlin.de/fachgebiete/wzm/forschung/forschung3/Magnetofluidisches%20Positioniersystem/view?searchterm=Hipper  nanoactuators], [http://www.ferrotec.com/products/ferrofluid/audio/audioBenefits.php loudspeakers], [   http://wood.phy.ulaval.ca/ferrofluids/homemade.php adaptive optics (liquid mirrors)],  
 
 
[http://wcms1.rz.tu-ilmenau.de/fakmb/fileadmin/template/fgtm/video/lysenko_kurz.avi  biologically inspired robots] .
 
[http://wcms1.rz.tu-ilmenau.de/fakmb/fileadmin/template/fgtm/video/lysenko_kurz.avi  biologically inspired robots] .
 
** [http://www.jaist.ac.jp/~shinya/english/image/theme2_fig.png cancer treatment, separation, ultrasensitive analysis, MRI]  
 
** [http://www.jaist.ac.jp/~shinya/english/image/theme2_fig.png cancer treatment, separation, ultrasensitive analysis, MRI]  
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The phase behaviour and microstructure of ferrofluid systems in reduced dimensions is not necessarily
 
The phase behaviour and microstructure of ferrofluid systems in reduced dimensions is not necessarily
equivalent to that of 3D systems. Despite the progress obtained in previous studies (Lomba2000, Weis2002b-2003, Duncan2004-2006, Tavares2006), the understanding of the phase behaviour and microstructure formation of ferrofluids in constrained geometries is only partial.
+
equivalent to that of 3D systems. In addition, thin-films and monolayers, have become recently a more successful experimental scenario to assert the existence of the clustering process (Klokkenburg2006, Butter2003, Puntes2001, Wen1999). In the experiments of Philipse and co-workers(Butter2003, Klokkenburg2006), images obtained by cryogenic transmission electron microscopy (cyro-TEM) give ample evidence of the existence of chain- and ring-like structures in ferrofluid monolayers, where all particles are trapped in one plane, but their magnetic moments are free to fluctuate in 3D (q2D monolayers).
  
Thin-films and monolayers, have become recently a more successful experimental scenario to assert the existence of the clustering process (Klokkenburg2006, Butter2003, Puntes2001, Wen1999). In the experiments of Philipse and co-workers(Butter2003, Klokkenburg2006), images obtained by cryogenic transmission electron microscopy (cyro-TEM) give ample evidence of
 
the existence of chain- and ring-like structures in ferrofluid monolayers, where all particles are trapped in one plane, but
 
their magnetic moments are free to fluctuate in 3D (q2D monolayers).
 
  
  
In recent years, several theoretical and computational works have
+
In recent years, several theoretical and computational works have been devoted to the study of ferrofluids in monolayers and
been devoted to the study of ferrofluids in monolayers and
+
thin-films. The thermodynamics, and magnetisation properties of quasi-two-dimensional (q2D) systems have been studied by Lomba et al. (Lomba2000), and Gao et al. (Gao1997).  Weis and co-workers (see (Weis2002b,Weis2003), and references therein), have performed Monte Carlo simulations of monolayers and systems of finite thickness involving dipolar interactions. They have shown that q2D dipolar systems, alone or in combination with other interactions, present a rich variety of structures, phases and phase transitions. In a recent q2D Monte Carlo study on dipolar hard spheres (DHS), Tavares et al. (Tavares2006) have reported  the structure of the fluid to be well described by an ideal mixture of self-assembling clusters at low and intermediate densities. Very recently,  Duncan-Camp (Duncan2006) have studied the kinetics of aggregation in monolayers using stochastic dynamics simulations. The results obtained in that work suggest that the conditions for defect-driven condensation (Tlusty2000) could be met by kinetic trapping, giving rise to a metastable phase transition between isotropic fluid phases. The structure formation and magnetic properties  of polydisperse ferrofluids in monolayers have been also recently addressed by theory and Monte Carlo simulations (Morimoto2003,Aoshima2004,Kristof2005).
thin-films. The thermodynamics, and magnetisation properties of
 
quasi-two-dimensional (q2D) systems have been studied by Lomba et
 
al. \cite{Lomba2000}, and Gao et al. \cite{Gao1997}.  Weis and
 
co-workers (see \cite{Weis2002b,Weis2003}, and references
 
therein), have performed Monte Carlo simulations of monolayers and
 
systems of finite thickness involving dipolar interactions. They
 
have shown that q2D dipolar systems, alone or in combination with
 
other interactions, present a rich variety of structures, phases
 
and phase transitions. In a recent q2D Monte Carlo study on
 
dipolar hard spheres (DHS), Tavares et al. \cite{Tavares2006} have
 
reported  the structure of the fluid to be well described by an
 
ideal mixture of self-assembling clusters at low and intermediate
 
densities. Very recently,  Duncan-Camp \cite{Duncan2006} have
 
studied the kinetics of aggregation in monolayers using stochastic
 
dynamics simulations. The results obtained in that work suggest
 
that the conditions for defect-driven condensation
 
\cite{Tlusty2000} could be met by kinetic trapping, giving rise to
 
a metastable phase transition between isotropic fluid phases. The
 
structure formation and magnetic properties  of polydisperse
 
ferrofluids in monolayers have been also recently addressed by
 
theory and Monte Carlo simulations
 
\cite{Morimoto2003,Aoshima2004,Kristof2005}.
 
  
 
+
Despite the progress obtained in previous studies, the understanding of the phase behaviour and microstructure formation of ferrofluids in constrained geometries is only partial.
== Modelling Ferrofluids ==
 
  
  

Revision as of 11:57, 4 January 2008

Fig1. Ferrofluid monolayer at low area fraction.
Fig2. Ferrofluid monolayer at high area fraction.

Ferrofluids under construction

What are Ferrofluids?

Dipolar magnetic fluids (also known as ferrofluids or ferrocolloids), are colloidal suspensions of ferromagnetic nanoparticles (typical sizes 10-20nm), usually stabilised by steric coatings (in non electrolyte carrier liquids) or by electrical double layers (in aqueous solutions). Sterical coatings are usualy made of a stabilizing dispersing agent (surfactant) which prevents particle agglomeration even when a strong magnetic field gradient is applied to the ferrofluid. The surfactant must be matched to the carrier type and must overcome the attractive van der Waals and magnetic forces between the particles. A typical ferrofluid may contain by volume 5% magnetic solid, 10% surfactant and 85% carrier.

Due to their size, ferrofluid particles can be considered as magnetic single-domains with a permanent magnetic moment $|\mathbf{m}|=m$ proportional to their volume $\pi \sigma_m^3/6$, where $\sigma_m$ is the diameter of the magnetic core of the particle.

To know more about the basics of ferrofluids, see for instancelink Ferrofluids in the Wikipedia.

Synthesis of ferrofluids

The idea of making a liquid with magnetic properties seems to date back to the 40´s. Nonetheless, it seems that was Stephen Papell Solomon (US Patent 3215572 ) working for NASA in the 60´s the first to develop an easy and effective way of preparing such colloidal systems. You can also prepare your own ferrofluids at home


Why are Ferrofluids interesting?

Ferrofluids are interesting for two fold reason:

  • Ferrofluids are systems exhibing anisotropic interactions leading to a very reach phase behaviour, rheological and magnetic properties. Thus ferrofluids are a paradigma of physical systems with anisotropic interactions.
  • The singular properties of ferrofluids in external magnetic fields have found application in many areas, ranging from engineering, to biomedical applications in cancer treatment (Rosensweig1985, Odenbach2002, Alexiou2003,Hilger2004, Scherer2005). Just a few examples:

biologically inspired robots .



Aggregating structures formed by Ferrofluids

Even in the absence of external fields, ferrofluids have a very complex microstructure, which is caused by the combination of interparticle interactions specific to magnetic fluids (see for instance figures 1 and 2). Ferrofluid particles are known to self-assemble into a variety of magnetic equilibrium structures which depend on several factors such as: system geometry, magnetic interactions, particle polydispersity, presence or absence of external fields, etc.

The number of probable cluster topologies in magnetic fluids is high: drops with high magnetic phase concentration (micron size), branched and fractal clusters (hundreds of nanometers in size), or chain- and ring-like structures (tens of nanometers). Signs of clustering process in ferrofluids at zero field are known for more than 40 years (Hess1966). Nonetheless, despite the large amount of clues obtained in subsequent studies (Shen2001,Donselaar1999,Cebula1983,Gazeau2002), a direct experimental proof of the existence of clusters like chains, rings, etc. has been elusive for many years, specially for those cases were dipole-dipole interactions were relatively week, like in magnetite nanoparticles ($Fe_3O_4$). Thus, due to the lack of conclusive experiments, the understanding of how dipole-dipole interactions influence the clustering process and determine the subsequent microstructure and phase behaviour of ferrofluids has become a challenge. In bulk ferrofluids, those aspects have been studied in detail through theoretical (Gennes1970, Jordan1973, Osipov1996, Zubarev1995, Tavares1997, Tavares1999, Roij1996, Tlusty2000, Morozov2002, Mendelev2004, Ivanov2004) and simulation (Weis1993, Levesque1994, Jund1995, Camp2000, Pshenichnikov2000, Wang2002, Wang2003, Holm2006) works. Comprehensive reviews on these subject for bulk systems are also available, see (Teixeira2000, Cabuil2000, Huke2004, Holm2005).


Ferrofluid Monolayers

The phase behaviour and microstructure of ferrofluid systems in reduced dimensions is not necessarily equivalent to that of 3D systems. In addition, thin-films and monolayers, have become recently a more successful experimental scenario to assert the existence of the clustering process (Klokkenburg2006, Butter2003, Puntes2001, Wen1999). In the experiments of Philipse and co-workers(Butter2003, Klokkenburg2006), images obtained by cryogenic transmission electron microscopy (cyro-TEM) give ample evidence of the existence of chain- and ring-like structures in ferrofluid monolayers, where all particles are trapped in one plane, but their magnetic moments are free to fluctuate in 3D (q2D monolayers).


In recent years, several theoretical and computational works have been devoted to the study of ferrofluids in monolayers and thin-films. The thermodynamics, and magnetisation properties of quasi-two-dimensional (q2D) systems have been studied by Lomba et al. (Lomba2000), and Gao et al. (Gao1997). Weis and co-workers (see (Weis2002b,Weis2003), and references therein), have performed Monte Carlo simulations of monolayers and systems of finite thickness involving dipolar interactions. They have shown that q2D dipolar systems, alone or in combination with other interactions, present a rich variety of structures, phases and phase transitions. In a recent q2D Monte Carlo study on dipolar hard spheres (DHS), Tavares et al. (Tavares2006) have reported the structure of the fluid to be well described by an ideal mixture of self-assembling clusters at low and intermediate densities. Very recently, Duncan-Camp (Duncan2006) have studied the kinetics of aggregation in monolayers using stochastic dynamics simulations. The results obtained in that work suggest that the conditions for defect-driven condensation (Tlusty2000) could be met by kinetic trapping, giving rise to a metastable phase transition between isotropic fluid phases. The structure formation and magnetic properties of polydisperse ferrofluids in monolayers have been also recently addressed by theory and Monte Carlo simulations (Morimoto2003,Aoshima2004,Kristof2005).

Despite the progress obtained in previous studies, the understanding of the phase behaviour and microstructure formation of ferrofluids in constrained geometries is only partial.


Our Current Research

  • Ferrofluid monolayers: monodisperse particles. [Link 1]
  • Ferrofluid monolayers: bidisperse particles. [Link 2]
  • Structure factors of ferrofluids in the low-density low-aggregating limit [Link 3]

Scientists

Collaborators

  • Group of Prof. Alexey Ivanov, Ekaterimburg.

Publications

Links